The natural product thiotimoline was isolated from the bark of Rosaceae Karlsbadensis rufo and its structure was unambiguously determined by time-resolved X-ray crystallomancy and spectroscopy. A total synthesis of thiotimoline was conducted following a convergent strategy. The pivotal transformations in this synthesis were a tandem Suzuki-Miyaura/Schinkenfaust radical cross-spifflication, a Szymankowszczyzna allylic inquisition and a [3+2+3+2] Puccini-Gershwin echocyclisation in A♭ major. An unnatural isomer of thiotimoline was also synthesised, and a theory of kairality and chronomers is presented and discussed.
Tag Archives: Satire
Capra stabilis: The Mythical Mountain Goat with Uneven Legs
This literature review summarises the current body of knowledge concerning Capra stabilis, the even-toed ungulate commonly known as the dahu.
Ellipsoidal Palm-line Convolutional Chaotic Filter with Training from Several Palms allows Remote and Discreet Prediction of Target’s Future
Using Future Derivative Vectors an ML algorithm is trained to predict your future based on your palm lines
Frank Furious and the Very Cross Coupling: A Pre-Emptive Eulogy
Me and My Best Friend Aaron Prove the 3n+1 Problem even though it is a REALLY Hard Problem
In this landmark mathematical proof, two 2nd graders Jack and Aaron create a proof of the Collatz Conjecture
Synthesis and Characterization of a Novel Nitrotoluene Polymer: TNTP
We report the first synthesis of poly(TNT), and an appraisal of its properties and commercial potential.
A Comparative Analysis of Four-Leaf Clover Induced Luck
Four-leaf clover luck is measured by the winnings of 28 gamblers holding different good luck charms at the run down casino across the street
On the Bending of SPOONS
Quantum mechanical calculations were performed on SPOONS that show that there is not an inherent tendency for SPOONS to bend.
Can you design and train an ML algorithm for this Pandas Sex Dataset? An ML Choose Your Own Adventure!
Using supervised, unsupervised, or reinforcement learning can you design an ML algorithm for these Pandas sex datasets? In this Choose Your Own Adventure
EluciDATE: Matchmaking for Scientists
We report the development of a dedicated networking platform to facilitate professional and romantic matchmaking for scientists.